Steam reforming of methanol over copper-containing catalysts: Influence of support material on microkinetics

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Steam reforming of methanol over copper-containing catalysts: influence of support material on microkinetics

Steam reforming of methanol (SRM) was investigated over copper-containing catalysts supported on four different oxides and mixed oxides: Cu/ZnO/Al2O3, Cu/ZrO2/CeO2, Cu/SiO2 and Cu/Cr2O3/Fe2O3. After observing slight differences in the way of catalyst aging and experimental exclusion of mass transport limitation effects, a detailed kinetic study was carried out at 493 K. The dependence of the re...

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Effect of Pt on Zn-Free Cu-Al Catalysts for Methanol Steam Reforming to Produce Hydrogen

Steam reforming of methanol can be considered as an attractive reaction aiming at hydrogen production for PEM fuel cells. Although Cu/Al-contained catalysts are considerably evaluated in this reaction, further evaluation is essential to evaluate the impact of some promoters like Pt in order to find a comprehensively optimized catalyst. Pt promoter is employed with different methods in this ...

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Steam reforming of methanol (SRM) was investigated over Cu/ZrO2/CeO2 (CZC) catalysts prepared via a novel synthetic method based on coprecipitation and polymer templating. Structural characterization of the samples was performed by N2 adsorption-desorption, N2O decomposition, and X-ray diffraction. The variation of the Cu loading resulted in an increased Cu crystallite size and a decreased spec...

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ژورنال

عنوان ژورنال: Journal of Catalysis

سال: 2007

ISSN: 0021-9517

DOI: 10.1016/j.jcat.2006.11.031